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Synthesis of (polyfluoroalkyl)pyrroles and -porphyrins

Aromatic- Pyrrole- porphyrin ring synthesis - …

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Porphyrins/chemical synthesis* Pyrroles*

Notes: a) The rate limiting synthetic step is the formation from glycine and succinyl coA of d- aminolevulinic acid (ALA).
b) Several key steps take place in mitochondria or on mitochondrial membranes.
c) Porphyrinogens are colorless, unstable, ringed tetrapyrroles that are readily and irreversibly oxidized to red, stable porphyrins, which are excreted in urine or bile.
d) Only one porphyrin, protoporphyrin IX, is retained and is converted to heme.

Aromatic- Pyrrole- porphyrin ring synthesis : Previous: Next: Report error with mechanism

N2 - Cu(I)-mediated annulation of meso,meso-1,3-butadiyne-bridged Zn(II) diporphyrin with various amines efficiently provided meso,meso'-pyrrole-bridged Zn(II) diporphyrins. Notable intramolecular electronic interactions in these diporphyrins were observed. A starburst porphyrin pentamer was synthesized via Suzuki-Miyaura coupling of N-bromophenylpyrrole-bridged diporphyrin and meso,meso'-diborylated porphyrin.

IN VITRO PYRROLE AND PORPHYRIN SYNTHESIS IN ..

Synthesis of meso, meso-pyrrole-bridged diporphyrins by …

Cu(I)-mediated annulation of meso,meso-1,3-butadiyne-bridged Zn(II) diporphyrin with various amines efficiently provided meso,meso'-pyrrole-bridged Zn(II) diporphyrins. Notable intramolecular electronic interactions in these diporphyrins were observed. A starburst porphyrin pentamer was synthesized via Suzuki-Miyaura coupling of N-bromophenylpyrrole-bridged diporphyrin and meso,meso'-diborylated porphyrin.

AB - Cu(I)-mediated annulation of meso,meso-1,3-butadiyne-bridged Zn(II) diporphyrin with various amines efficiently provided meso,meso'-pyrrole-bridged Zn(II) diporphyrins. Notable intramolecular electronic interactions in these diporphyrins were observed. A starburst porphyrin pentamer was synthesized via Suzuki-Miyaura coupling of N-bromophenylpyrrole-bridged diporphyrin and meso,meso'-diborylated porphyrin.

Synthesis of meso, meso-pyrrole-bridged diporphyrins by Cu ..

JCI - IN VITRO PYRROLE AND PORPHYRIN SYNTHESIS …

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  • Pragi Arora* 1, Varun Arora 1, H.S

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