Metal-free methods in the synthesis of macrocyclic Schiff bases.
(2011): The Use of Hydrogenated Schiff Base Ligands in the Synthesis of Multi-metallic Compounds II.
(1999): Medicinal Chemistry of Schiff Base ..
Gupta, "Synthesis and Antimicrobial Profile of Newer Schiff Bases and Thiazolidinone Derivatives", WASET- International Journal of Chemical, Nuclear, Metallurgical and Materials Engineering, Vol.
Because of the relative easiness of preparation, synthetic flexibility, and the special property of C=N group, Schiff bases are generally excellent chelating agents [2, 4, 5, 6] especially when a functional group like –OH or –SH is present close to the azomethine group so as to form a five or six membered ring with the metal ion.
This intermediate general chemistry ..
One representative group of macrocycles comprise Schiff base macrocyclic compounds, which are synthesized by the reaction of dicarbonyl compounds with diamines via a well-understood mechanism [, ].
We also noted that a representative Schiff base macrocycle, containing a 2, 6-diamidopyridine subunit, could have an important role to play in the molecular recognition of organic molecules and inorganic anions [-].
Biological activities of Schiff base and ..
Schiffbase macrocycles 1 and 2 were synthesized by the Schiff base condensation of pyridine-2, 6-dicarboxamide with 1, 10-bis(2'-formylpheny-loxy)decane in the presence of phosphoric acid a one-pot process.
Experimental Synthesis of the Schiff-base macrocycle 1 and 2: Precursor pyridine-2, 6-dicarboxamide was prepared from the reaction of commercial pyridine-2, 6-dicarbonyl dichloride with 2-nitrobenzenamine according to a literature procedure for similar structures .
Principles of Organic Synthesis - Home - Michigan …
Principles of Organic Synthesis ..
Catalyst-free Preparation of Melamine-Based Microporous Polymer Networks through Schiff Base Chemistry
Schiff bases and their complexes
Advances in Chemistry Research II: Corrosion Inhibition Study of a Heterocyclic Schiff Base Derived from Isatin
Synthesis and Antimicrobial Activity of Carbohydrate …
Schiff-base macro cycles have been of great importance in macro cyclic and supra molecular chemistry
we report herein the synthesis of Schiff ..
Here, we report the synthesis and characterization of two Schiff base macrocycles containing a 2, 6-diamidopyridine subunit from the condensation of the diamine and dialdehyde precursors shown in .
The Chemistry of Imines. - Chemical Reviews (ACS …
The regioselective preparation of 2,5-disubstituted pyrroles, useful structural scaffolds, is important. To this end, a protocol based on a stepwise iododesilylation and a subsequent coupling reaction, involving a 6-step pathway starting from the simplest pyrrole, has been realised. This methodology can be widely used in the synthesis of drugs, molecular wires, and high-molecular-weight polymers.
methyl anthranilate 134-20-3 - The Good Scents …
All the chemicals used were of analytical grade and were used without further purification. CT-DNA and pUC19 plasmid DNA were purchased from Sigma. Elemental analyses (carbon, hydrogen, nitrogen, oxygen and sulphur) were performed using a Perkin-Elmer 240 elemental analyzer. IR spectra of the Schiff base ligands and their complexes were recorded on a Shimadzu FT-IR-8300 instrument using KBr discs in the range of 4000–200cm−1. 1H-NMR spectra of the synthesized compounds were recorded on Bruker DRX-300 spectrometer using DMSO-d6 as solvent and TMS as the internal standard. Molar conductivity measurements were recorded on a CM-82T Elico conductivity bridge in DMSO. Thermogravimetric analyses data were measured from room temperature to 700°C at a heating rate of 20°C/min. The data were recorded on a Shimadzu TG-50 thermobalance. Absorption spectra were recorded using a hp spectrophotometer (Agilent 8453).
Metabolism – Proteins | Biochemistry for Medics – …
Lara, et al., Synthesis, structural characterization and metal inclusion properties of 18-20-and 22-membered oxaazacyclophanes and oxaazacalix arene analogues:macrocyclic amine and Schiff base receptors with variable NxOy donor sets, Eur.
Glucose in Cell Culture | Sigma-Aldrich
However, in spite of such an importance the number of reports available on organotin(IV) complexes and their DNA binding properties is very few. As an extension of the studies of organotin(IV) complexes with Schiff bases [, ], we have now synthesized four organotin(IV) complexes with Schiff bases, 2-(2-hydroxybenzylideneamino)isoindoline-1,3-dione, and 4-(4-hydroxy-3-methoxybenzylideneamino-N-(pyrimidin-2-yl) benzenesulfonamide.
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